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Fill a large bowl with ice water and set aside.
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Bring a medium saucepan of water to a boil and add orange slices.
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Boil 1 minute then place in the bowl of ice water until cooled. Drain.
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In a large skillet over medium heat, bring 2 cups sugar, 2 cups water and 2 tablespoons orange juice just to a boil, and heat until sugar dissolves (stir occasionally).
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Turn heat to medium-low and place orange slices in the sugar-water in a single layer.
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Simmer (do not boil) the orange slices 45-60 minutes or until rinds are slightly translucent, turning every 15 minutes.
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Place orange slices on a cooling rack and allow to cool completely, (1 hour or overnight).
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If desired, sprinkle extra sugar over candied orange slices if you prefer the slices less sticky.
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Use immediately or keep orange slices refrigerated in an airtight container until ready to use.
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The orange slices can be kept up to 1 month and used as a garnish for many desserts.
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Reserve orange syrup, in the fridge, for another use being sure to discard after 2 weeks.
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Enjoy!